Thermal behavior and kinetics of crude oils at low heating rates by differential scanning calorimeter

Kok M. V.

FUEL PROCESSING TECHNOLOGY, cilt.96, ss.123-127, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 96
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1016/j.fuproc.2011.12.027
  • Dergi Adı: FUEL PROCESSING TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.123-127
  • Anahtar Kelimeler: Crude oil, Combustion, Kinetics, Differential scanning calorimeter, Thermal analysis, COMBUSTION KINETICS, ASPHALTENES, PYROLYSIS, RECOVERY, RESINS, DSC
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The objective of this research was to investigate thermal behavior and kinetics of different origin crude oils in limestone matrix by differential scanning calorimeter (DSC) at low heating rates. In DSC experiments, three distinct reaction regions were identified in all of the crude oil + limestone mixtures known as low temperature oxidation (LTO), fuel deposition (FD) and high temperature oxidation (HTO) respectively. Kinetic analysis of the crude oil samples was determined by different models known as ASTM. Borchard-Daniels and Ozawa. Higher activation energy values were obtained in high temperature oxidation region. (C) 2011 Elsevier B.V. All rights reserved.