AN EFFICIENT BUTENOLIDE ANNULATION VIA ALPHA'-CHLOROACETOXYLATION OF ENONES USING MANGANESE(III) ACETATE AND CHLOROACETIC ACID

DEMIR A., AKGUN H., TANYELI C., SAYRAC T., WATT D.

SYNTHESIS-STUTTGART, sa.9, ss.719-721, 1991 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 1991
  • Dergi Adı: SYNTHESIS-STUTTGART
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.719-721
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The alpha'-chloroacetoxylation of alpha,-beta-unsaturated ketones using manganese(III) acetate and chloroacetic acid followed by Arbuzov reaction and intramolecular Horner-Emmons olefination provided a convenient synthesis of annulated 2-buten-4-olides.